A study of free energy relationships in the urea-sodium sulfate-water system.

نویسندگان

  • E E Schrier
  • R A Robinson
چکیده

Activity coefficients for each of the components, urea and sodium sulfate, in their ternary mixtures with water have been obtained using the isopiestic vapor pressure method over the concentration ranges 0 to 19.4 molal urea and 0 to 2.4 molal Na2S04. At the lower molalities of the solutes, there is mutual salting-in of the components which changes to salting-out at 0.4 molal Na2SQ4 and 5 molal urea. These results are considered as a model for certain interactions in the denaturation of proteins by electrolytes.

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عنوان ژورنال:
  • The Journal of biological chemistry

دوره 245 9  شماره 

صفحات  -

تاریخ انتشار 1970